No.

You can only 'gift' new games or parts of special offers that you already own (like with the orange box) to people on steam.
Makes sense from a business standpoint (if you're Valve), but yeah, I wish I could give away or sell on my old games.
And unfortunately there can be no second-hand market (not even with a % of every sale going to Valve) on a digital platform, what with there not being any wear and tear on media carriers or key troubles.